| Literature DB >> 16930038 |
John T Colyer1, Neil G Andersen, Jason S Tedrow, Troy S Soukup, Margaret M Faul.
Abstract
A variety of N-tert-butanesulfinyl imines were reduced with NaBH4 in THF containing 2% water to provide the corresponding secondary sulfinamides in high yield and diastereoselectivity. By using the same sulfinyl imine starting materials and changing the reductant to L-Selectride, the stereoselectivity could be efficiently reversed to afford the opposite product diastereomer in high yield and selectivity.Entities:
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Year: 2006 PMID： 16930038 DOI： 10.1021/jo0609834
Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354