| Literature DB >> 16925417 |
Masaharu Sugiura1, Chieko Mori, Shu Kobayashi.
Abstract
A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with high functional group tolerance has been attained in this transformation.Entities:
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Year: 2006 PMID： 16925417 DOI： 10.1021/ja064106r
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419