Dispersion of the ordinary refractive indices of smectic liquid crystals in free standing films.

The ordinary refractive indices of some smectic-A liquid crystals have been measured by means of interference spectra of free standing films as a function of wavelength and temperature. Numerical data are presented for further use. In the Sm-C phase one of the principal indices can be measured. If the three principal indices in the Sm-C phase would be known the tilt angle could be measured by means of the interference technique with high precision. Predictions of the refractive index of liquid crystals based on quantum chemical calculations of polarizabilities are presented. Using an expression derived by de Jeu and Bordewijk [J. Chem. Phys. 68, 109 (1978)] values for the principal refractive indices have been calculated that can be compared with our experimental results.