Literature DB >> 16906807

Effective classical partition functions with an improved time-dependent reference potential.

Benoit Palmieri1, David Ronis.   

Abstract

The original Feynman-Kleinert [Phys. Rev. A 34, 5080 (1986)] variational approach to Euclidean path integrals is improved by introducing a reference harmonic potential whose center is allowed to change with time. The motion of the center of the potential is varied such that the "effective potential" of Feynman and Kleinert is minimized and leads to an equation of motion for the classical path in the reference system that closely reproduces the "exact" average path. The formalism is applied to the double-well potential V(x)=-x(2)/2 + gx(4)/4+1/4g. This modification improves the accuracy of the approximate quantum-mechanical distribution function and, to a larger extent, the density matrix.

Year:  2006        PMID: 16906807     DOI: 10.1103/PhysRevE.73.061105

Source DB:  PubMed          Journal:  Phys Rev E Stat Nonlin Soft Matter Phys        ISSN: 1539-3755


  2 in total

1.  An automated integration-free path-integral method based on Kleinert's variational perturbation theory.

Authors:  Kin-Yiu Wong; Jiali Gao
Journal:  J Chem Phys       Date:  2007-12-07       Impact factor: 3.488

2.  A Systematic Approach for Computing Zero-Point Energy, Quantum Partition Function, and Tunneling Effect Based on Kleinert's Variational Perturbation Theory.

Authors:  Kin-Yiu Wong; Jiali Gao
Journal:  J Chem Theory Comput       Date:  2008-09-09       Impact factor: 6.006

  2 in total

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