Literature DB >> 16901128

Cationic Rh(I) catalyst in fluorinated alcohol: mild intramolecular cycloaddition reactions of ester-tethered unsaturated compounds.

Akio Saito1, Takamitsu Ono, Yuji Hanzawa.   

Abstract

In fluorinated alcohols, the cationic Rh(I) species, which is derived from [Rh(COD)Cl]2 and AgSbF6, efficiently catalyzed intramolecular [4+2] cycloaddition reactions of ester-tethered 1,3-diene-8-yne derivatives. The catalytic system was also effective in intramolecular [5+2] cycloaddition reactions of ester-tethered omega-alkynyl vinylcyclopropane compounds.

Entities:  

Mesh:

Substances:

Year:  2006        PMID: 16901128     DOI: 10.1021/jo060827x

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Reactivity and chemoselectivity of allenes in Rh(I)-catalyzed intermolecular (5 + 2) cycloadditions with vinylcyclopropanes: allene-mediated rhodacycle formation can poison Rh(I)-catalyzed cycloadditions.

Authors:  Xin Hong; Matthew C Stevens; Peng Liu; Paul A Wender; K N Houk
Journal:  J Am Chem Soc       Date:  2014-11-24       Impact factor: 15.419

2.  Computational ligand design in enantio- and diastereoselective ynamide [5+2] cycloisomerization.

Authors:  R N Straker; Q Peng; A Mekareeya; R S Paton; E A Anderson
Journal:  Nat Commun       Date:  2016-01-05       Impact factor: 14.919

  2 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.