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Literature DB >> 16883403

Metal-organic frameworks incorporating Cu3(mu3-OH) clusters.

Andrey B Lysenko¹, Evgen V Govor, Harald Krautscheid, Konstantin V Domasevitch.

Abstract

Interaction of 4,4-bi(1,2,4-triazole) (btr) with copper(II) chloride (bromide) in aqueous or aqueous alcohol media led to a series of coordination polymers featuring the formation of mu 3-hydroxotricopper(II) clusters and their integration into 3D frameworks. These unprecedented structures originate in the propagation of trigonal hydroxotricopper(II) clusters bridged by tri- or tetradentate organic ligands. Complex [{Cu3(mu3-OH)}{Cu3(mu3-O)}(mu4-btr)3(H2O)4(OH)2Cl6]Cl.0.5H2O adopts a structure of SrSi2 topology, with eight-fold interpenetration of the coordination frameworks. The structure of [{Cu3(mu3-OH)}2(mu3-btr)6(mu4-btr)(mu-X)X4]X5.nH2O (X = Br, n = 6; X = Cl, n = 8) involves 2D coordination layers [{Cu3(mu3-OH)}(mu3-btr)3]n with an exceptional (3,6)-net topology, which are cross-linked by tetradentate btr ligands and bridging chloride (bromide) ions.

Entities: Chemical

Year: 2006 PMID： 16883403 DOI： 10.1039/b604804h

Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390

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Cited

3 in total

1. "Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu(3)(μ(3)-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice"

Authors: Marlyn Rivera-Carrillo; Indranil Chakraborty; Raphael G Raptis
Journal: Cryst Growth Des Date: 2010-01-01 Impact factor: 4.076

2. Crystal structure of poly[tetra-μ-chlorido-tetra-chlorido-bis-(μ₃-4,4'-bi-1,2,4-triazole-κ³ N ¹:N ²:N ^1')(μ-4,4'-bi-1,2,4-triazole-κ³ N ¹:N ^1')tetra-copper(II)].

Authors: Kostiantyn V Domasevitch; Andrey B Lysenko
Journal: Acta Crystallogr E Crystallogr Commun Date: 2019-05-14

3. Crystal structure of poly[[(μ₃-hydroxido-κ³ O:O:O)(μ₃-selenato-κ³ O ¹:O ²:O ³)tris-[μ₃-2-(1,2,4-triazol-4-yl)acetato-κ³ N ¹:N ²:O]tricopper(II)] dihydrate].

Authors: Kostiantyn V Domasevitch; Andrey B Lysenko
Journal: Acta Crystallogr E Crystallogr Commun Date: 2019-07-16

3 in total

Metal-organic frameworks incorporating Cu3(mu3-OH) clusters.

1. "Systematic Synthesis of a Metal Organic Framework Based on Triangular Cu(3)(μ(3)-OH) Secondary Building Units: From a 0-D Complex, to an 1-D Chain and a 3-D Lattice"

2. Crystal structure of poly[tetra-μ-chlorido-tetra-chlorido-bis-(μ3-4,4'-bi-1,2,4-triazole-κ3 N 1:N 2:N 1')(μ-4,4'-bi-1,2,4-triazole-κ3 N 1:N 1')tetra-copper(II)].

3. Crystal structure of poly[[(μ3-hydroxido-κ3 O:O:O)(μ3-selenato-κ3 O 1:O 2:O 3)tris-[μ3-2-(1,2,4-triazol-4-yl)acetato-κ3 N 1:N 2:O]tricopper(II)] dihydrate].

2. Crystal structure of poly[tetra-μ-chlorido-tetra-chlorido-bis-(μ₃-4,4'-bi-1,2,4-triazole-κ³ N ¹:N ²:N ^1')(μ-4,4'-bi-1,2,4-triazole-κ³ N ¹:N ^1')tetra-copper(II)].

3. Crystal structure of poly[[(μ₃-hydroxido-κ³ O:O:O)(μ₃-selenato-κ³ O ¹:O ²:O ³)tris-[μ₃-2-(1,2,4-triazol-4-yl)acetato-κ³ N ¹:N ²:O]tricopper(II)] dihydrate].