Literature DB >> 16883398

The first complexes and cyclodimerisations of methylphosphaalkyne (P[triple bond]CMe).

Cameron Jones1, Christian Schulten, Andreas Stasch.   

Abstract

The first complexes and cyclodimerisations of methylphosphaalkyne, P[triple bond]CMe, are reported to arise from its reactions with a range of platinum(0) complexes and [W(CO)5(THF)]. A number of differences between the chemistry of this phosphaalkyne and that of its bulkier analogues have been highlighted and explained on steric grounds.

Entities:  

Year:  2006        PMID： 16883398     DOI： 10.1039/b607489h

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  Isolation of an Elusive Phosphametallacyclobutadiene and Its Role in Reversible Carbon-Carbon Bond Cleavage.

Authors:  Vineet K Jakhar; Alec M Esper; Ion Ghiviriga; Khalil A Abboud; Christian Ehm; Adam S Veige
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-07       Impact factor: 16.823

2.  Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex.

Authors:  Amélie Nicolay; Micah S Ziegler; David W Small; Rebecca Grünbauer; Manfred Scheer; T Don Tilley
Journal:  Chem Sci       Date:  2019-12-19       Impact factor: 9.825
  2 in total

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