| Literature DB >> 16866502 |
Srinivas Hotha1, Sudhir Kashyap.
Abstract
The advantages of stable glycosyl donors for saccharide coupling are many, and we describe herein the utility of propargyl glycosides for anomeric activation and glycoside synthesis exploiting the alkynophilicity of AuCl3. Various aglycones were reacted with propargyl glycosides, resulting in the formation of an alpha,beta-mixture of glycosides and disaccharides in good yields.Entities:
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Year: 2006 PMID： 16866502 DOI： 10.1021/ja062425c
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419