Literature DB >> 16855702

Enantioselective synthesis of beta-amino esters and its application to the synthesis of the enantiomers of the antidepressant Venlafaxine.

Huw M L Davies1, Aiwu Ni.   

Abstract

Beta-amino esters are readily formed from the rhodium(II) prolinate-catalyzed intermolecular C-H insertion between methyl aryldiazoacetates and a bis-silyl protected methylamine.

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Year:  2006        PMID： 16855702     DOI： 10.1039/b605047f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  If C-H bonds could talk: selective C-H bond oxidation.

Authors:  Timothy Newhouse; Phil S Baran
Journal:  Angew Chem Int Ed Engl       Date:  2011-03-16       Impact factor: 15.336

Review 2.  Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion.

Authors:  Huw M L Davies; James R Manning
Journal:  Nature       Date:  2008-01-24       Impact factor: 49.962

3.  Finding Opportunities from Surprises and Failures. Development of Rhodium-Stabilized Donor/Acceptor Carbenes and Their Application to Catalyst-Controlled C-H Functionalization.

Authors:  Huw M L Davies
Journal:  J Org Chem       Date:  2019-10-10       Impact factor: 4.354

4.  Rh(iii)-catalyzed regioselective intermolecular N-methylene Csp3-H bond carbenoid insertion.

Authors:  Haisheng Xie; Zongren Ye; Zhuofeng Ke; Jianyong Lan; Huanfeng Jiang; Wei Zeng
Journal:  Chem Sci       Date:  2017-11-27       Impact factor: 9.825
  4 in total

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