Literature DB >> 16853849

Strong covalent hydration of terephthalaldehyde.

Melek S Baymak1, Kellie L Vercoe, Petr Zuman.   

Abstract

Spectrophotometric and electroanalytical studies indicate that one of the formyl groups of terephthalaldehyde in aqueous solution is present in about 23% as a geminal diol. Stronger covalent hydration of CHO in terephthalaldehyde than in p-nitrobenzaldehyde is attributed to a strong resonance interaction between the two formyl groups.

Entities:  

Year:  2005        PMID: 16853849     DOI: 10.1021/jp054475u

Source DB:  PubMed          Journal:  J Phys Chem B        ISSN: 1520-5207            Impact factor:   2.991


  1 in total

1.  A theoretical investigation on the proton transfer tautomerization mechanisms of 2-thioxanthine within microsolvent and long range solvent.

Authors:  Hong-Jiang Ren; Ke-He Su; Yan Liu; Xiao-Jun Li; Jun Xiao; Yan-Li Wang
Journal:  J Mol Model       Date:  2013-05-08       Impact factor: 1.810

  1 in total

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