| Literature DB >> 16848461 |
Cédric Genet1, Steven J Canipa, Peter O'Brien, Sven Taylor.
Abstract
The catalytic asymmetric synthesis of planar chiral ferrocenes and P-stereogenic phosphines and bisphosphines (important classes of chiral ligands for metal-catalyzed asymmetric processes) is successfully demonstrated using n-BuLi or s-BuLi in combination with substoichiometric quantities (0.1-0.5 equiv) of (-)-sparteine or the (+)-sparteine surrogate.Entities:
Year: 2006 PMID： 16848461 DOI： 10.1021/ja062616f
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419