Literature DB >> 16848424

A new Ru-catalyzed cascade reaction forming polycyclic cyclohexadienes from 1,6-diynes and alkenes.

Jesús A Varela1, Silvia G Rubín, Carlos Gonzalez-Rodríguez, Luis Castedo, Carlos Saa.   

Abstract

Functionalized bicyclic 1,3-cyclohexadienes can be easily prepared by a new cascade reaction which involves the Ru-catalyzed addition of acyclic alkenes to 1,6-diynes to give (Z)-hexatrienes, followed by a pure thermal 6e-pi electrocyclization.

Entities:  

Year:  2006        PMID: 16848424     DOI: 10.1021/ja057306w

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  6 in total

1.  Rh(i)-catalyzed dimerization of ene-vinylidenecyclopropanes for the construction of spiro[4,5]decanes and mechanistic studies.

Authors:  Chao Ning; Kang-Hua Rui; Yin Wei; Min Shi
Journal:  Chem Sci       Date:  2022-06-01       Impact factor: 9.969

Review 2.  Ruthenium-Catalyzed Cycloadditions to Form Five-, Six-, and Seven-Membered Rings.

Authors:  Rosalie S Doerksen; Tomáš Hodík; Guanyu Hu; Nancy O Huynh; William G Shuler; Michael J Krische
Journal:  Chem Rev       Date:  2021-02-12       Impact factor: 60.622

3.  Neutral chiral cyclopentadienyl Ru(ii)Cl catalysts enable enantioselective [2+2]-cycloadditions.

Authors:  D Kossler; N Cramer
Journal:  Chem Sci       Date:  2017-01-19       Impact factor: 9.825

4.  Intermolecular oxidative decarbonylative [2 + 2 + 2] carbocyclization of N-(2-ethynylaryl)acrylamides with tertiary and secondary alkyl aldehydes involving C(sp3)-H functionalization.

Authors:  Yang Li; Gao-Hui Pan; Ming Hu; Bang Liu; Ren-Jie Song; Jin-Heng Li
Journal:  Chem Sci       Date:  2016-07-21       Impact factor: 9.825

5.  Elucidating the mechanism and origins of selectivity on catalyst-dependent cyclization reactions to form polycyclic indolines from a theoretical study.

Authors:  Yan Zhang; Yongsheng Yang; Ying Xue
Journal:  RSC Adv       Date:  2021-06-09       Impact factor: 4.036

6.  Bioorthogonal Azide-Thioalkyne Cycloaddition Catalyzed by Photoactivatable Ruthenium(II) Complexes.

Authors:  Alejandro Gutiérrez-González; Paolo Destito; José R Couceiro; Cibran Pérez-González; Fernando López; José L Mascareñas
Journal:  Angew Chem Int Ed Engl       Date:  2021-06-16       Impact factor: 16.823

  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.