Literature DB >> 16839176

Radical reduction of aromatic azides to amines with triethylsilane.

Luisa Benati1, Giorgio Bencivenni, Rino Leardini, Matteo Minozzi, Daniele Nanni, Rosanna Scialpi, Piero Spagnolo, Giuseppe Zanardi.   

Abstract

Aromatic azides are inert toward triethylsilane under thermal conditions in the presence of a radical initiator, but in the presence of additional catalytic amounts of tert-dodecanethiol, they afford anilinosilanes and thence the corresponding anilines in virtually quantitative yields.

Entities:  

Year:  2006        PMID： 16839176     DOI： 10.1021/jo060824k

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  4 in total

1.  Investigation of reactions postulated to occur during inhibition of ribonucleotide reductases by 2'-azido-2'-deoxynucleotides.

Authors:  Thao P Dang; Adam J Sobczak; Alexander M Mebel; Chryssostomos Chatgilialoglu; Stanislaw F Wnuk
Journal:  Tetrahedron       Date:  2012-04-21       Impact factor: 2.457

2.  EPR and pulsed ENDOR study of intermediates from reactions of aromatic azides with group 13 metal trichlorides.

Authors:  Giorgio Bencivenni; Riccardo Cesari; Daniele Nanni; Hassane El Mkami; John C Walton
Journal:  Beilstein J Org Chem       Date:  2010-08-09       Impact factor: 2.883

3.  A biomolecule-compatible visible-light-induced azide reduction from a DNA-encoded reaction-discovery system.

Authors:  Yiyun Chen; Adam S Kamlet; Jonathan B Steinman; David R Liu
Journal:  Nat Chem       Date:  2011-01-09       Impact factor: 24.427

4.  Switching on prodrugs using radiotherapy.

Authors:  Jin Geng; Yichuan Zhang; Quan Gao; Kevin Neumann; Hua Dong; Hamish Porter; Mark Potter; Hua Ren; David Argyle; Mark Bradley
Journal:  Nat Chem       Date:  2021-06-10       Impact factor: 24.427
  4 in total

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