Literature DB >> 16836368

Decarboxylative ring contractions and olefin insertions of vinyl oxazinanones.

Chao Wang1, Jon A Tunge.   

Abstract

[Structure: see text] 6-Vinyl oxazinanones undergo catalytic, diastereoselective, decarboxylative ring contraction to form vinyl azetidines in good yield. Performing the decarboxylation in the presence of Michael acceptors results in decarboxylative olefin insertion to provide diastereoenriched substituted vinyl piperidines.

Entities:  

Year:  2006        PMID： 16836368     DOI： 10.1021/ol0610744

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  5 in total

Review 1.  Transition metal-catalyzed decarboxylative allylation and benzylation reactions.

Authors:  Jimmie D Weaver; Antonio Recio; Alexander J Grenning; Jon A Tunge
Journal:  Chem Rev       Date:  2011-01-14       Impact factor: 60.622

2.  Asymmetric cycloadditions of palladium-polarized aza-o-xylylenes.

Authors:  Chao Wang; Jon A Tunge
Journal:  J Am Chem Soc       Date:  2008-06-06       Impact factor: 15.419

3.  Iridium(I)-Catalyzed Regio- and Enantioselective Allylic Amidation.

Authors:  Om V Singh; Hyunsoo Han
Journal:  Tetrahedron Lett       Date:  2007-10-01       Impact factor: 2.415

4.  Decarboxylative Cyclizations and Cycloadditions of Palladium-polarized Aza-ortho-Xylylenes.

Authors:  Chao Wang; Nirmal Pahadi; Jon A Tunge
Journal:  Tetrahedron       Date:  2009-06-27       Impact factor: 2.457

5.  Ruthenium-catalyzed decarboxylative C-S cross-coupling of carbonothioate: synthesis of allyl(aryl)sulfide.

Authors:  Ren-Hua Zheng; Hai-Chang Guo; Ting-Ting Chen; Qing Huang; Guo-Bo Huang; Hua-Jiang Jiang
Journal:  RSC Adv       Date:  2018-07-12       Impact factor: 3.361
  5 in total

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