Directing the self-assembly of nanocrystals beyond colloidal crystallization.

This article gives an overview of recent progress in the self-assembly of nanocrystals. Classic self-assembly of nanocrystals, so-called colloidal crystallization driven by van der Waals interactions, is highlighted first with an emphasis on the recent realization of binary colloidal crystals. Next, new developments in the integration of nanocrystals into clusters based on electrostatic interactions, hydrogen bonding and dipole-dipole interactions are summarized, shedding light on the defined control of the interactions between the nanocrystals. Finally, the fabrication of heterogenous nanocrystals, obtained via either phase selective modification at the water/oil interface or facet-selective crystal growth on non-spherical nanocrystals is discussed. These last materials may provide significant building blocks for mimicking molecular self-assembly.