Relative tropospheric photolysis rates of HCHO, H13CHO, HCH18O, and DCDO measured at the European photoreactor facility.

The relative photolysis rates of HCHO, H13CHO, HCH18O, and DCDO were studied in pseudo-natural tropospheric conditions in July 2003 at the European Photoreactor Facility (EUPHORE) in Valencia, Spain. The photolytic decay of HCHO, H13CHO, and HCH18O is measured relative to DCDO by long path FT-IR detection during the course of about 3 h of sunlight. The relative photolysis rates obtained are as follows: JH13CHO/JHCHO = 0.894 +/- 0.006, JHCH18O/JHCHO = 0.911 +/- 0.011, and JDCDO/JHCHO = 0.597 +/- 0.001. The errors represent 1sigma and do not include possible systematic errors. The atmospheric implications of the large isotope effects in the photolysis of formaldehyde are discussed.