Literature DB >> 16832519

Unanticipated formation of ortho-sulfone substituted phenols by anionic thia-Fries rearrangement of (aryl triflate)tricarbonylchromium complexes.

Zhirong Zhao1, Josef Messinger, Uwe Schön, Rudolf Wartchow, Holger Butenschön.   

Abstract

Tricarbonylchromium complexes of aryl triflates undergo base-mediated anionic thia-Fries rearrangements to generate push-pull substituted [ortho-hydroxyaryl(trifluoromethylsulfonyl)phenol]tricarbonylchromium complexes under very mild reaction conditions.

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Year:  2006        PMID： 16832519     DOI： 10.1039/b606092g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  2 in total

1.  Phenyl Sulfones: A Route to a Diverse Family of Trisubstituted Cyclohexenes from Three Independent Nucleophilic Additions.

Authors:  Spenser R Simpson; Paolo Siano; Daniel J Siela; Louis A Diment; Brian C Song; Karl S Westendorff; Megan N Ericson; Kevin D Welch; Diane A Dickie; W Dean Harman
Journal:  J Am Chem Soc       Date:  2022-05-20       Impact factor: 16.383

2.  A bioinspired and biocompatible ortho-sulfiliminyl phenol synthesis.

Authors:  Feng Xiong; Liang Lu; Tian-Yu Sun; Qian Wu; Dingyuan Yan; Ying Chen; Xinhao Zhang; Wei Wei; Yi Lu; Wei-Yin Sun; Jie Jack Li; Jing Zhao
Journal:  Nat Commun       Date:  2017-06-19       Impact factor: 14.919
  2 in total

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