Kinetic monitoring of electrophoretically induced solute reaction by axial absorption detection with liquid-core waveguide.

Teflon AF-2400 capillary has been used for capillary electrophoretic separation as well as for liquid-core waveguide for axial absorption detection. This separation/detection scheme has allowed continuous monitoring of electrophoretically induced reactions. In this paper, the decomposition of Cd2+ complex with 4-(2-pyridylazo)resorcinol has been tested, and its decomposition kinetics has been studied. A simple modeling has predicted the single-exponential decay of the absorbance detected by the present axial absorption detector and has allowed the estimation of the decomposition rate constant for this reaction.