Crystal bridge formation marks the transition to rigidity in a thin lubrication film.

We report that the rheological transition in a thin lubrication film of dodecane from bulk to high viscosity states as the thickness is decreased is the result of a novel structural transition. Using nonequilibrium molecular dynamics simulations we find that the initial increase in viscosity as the film thins is due to the formation of isolated crystalline bridges between the surfaces. As the thickness decreases further, these bridges increase in number and organize themselves into a tetratic order in the plane of the surface. We show that this ordered state melts at a temperature of 350 K.