| Literature DB >> 16802802 |
Masatoshi Shibuya1, Masaki Tomizawa, Iwao Suzuki, Yoshiharu Iwabuchi.
Abstract
Development of a stable nitroxyl radical class of catalysts, 2-azaadamantane N-oxyl (AZADO) and 1-Me-AZADO, for highly efficient oxidation of alcohols is described. AZADO and 1-Me-AZADO exhibit superior catalytic proficiency to TEMPO, converting various sterically hindered alcohols to the corresponding carbonyl compounds in excellent yields.Entities:
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Year: 2006 PMID： 16802802 DOI： 10.1021/ja0620336
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419