| Literature DB >> 16802801 |
Mason R Haneline1, Alan F Heyduk.
Abstract
Carbon-carbon bond-forming reductive elimination of biphenyl is observed upon two-electron oxidation of the [ZrIVPh2(ap)2]2- dianion. Crossover experiments confirm that the C-C bond-forming step occurs at a single zirconium metal center. The reactivity is enabled by the participation of a redox-active amidophenolate ligand set.Entities:
Year: 2006 PMID: 16802801 DOI: 10.1021/ja061107a
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419