Thermally induced polytype transformations among the layered double hydroxides (LDHs) of Mg and Zn with Al.

The hydrotalcite-like layered double hydroxide (LDH) of Mg with Al shows dramatic changes in the peaks arising from the (h0l)/(0kl) family of reflections in its powder X-ray diffraction pattern during thermal treatment. DIFFaX simulations show that these changes arise due to the transformation of the disordered 3R1 polytype into the 1H polytype on dehydration. The 1H polytype is an essential precursor to the decomposition reaction, which results in the formation of an oxide residue with the rock salt structure. In contrast, the LDH of Zn with Al does not undergo any such transformation, retaining the structure of the 3R1 polytype until decomposition into the oxide residue. Given the poor octahedral site preference of the Zn2+ ion, the 1H polytype is neither structurally stable nor is it topochemically necessary for the thermal decomposition of the Zn-Al LDH, the end product of the decomposition reaction being an oxide with the wurtzite structure.