| Literature DB >> 16787051 |
Carsten Strohmann1, Klaus Lehmen, Stefan Dilsky.
Abstract
Treatment of Me2Si(CH2CH=CH2)(CH2NC5H10) with 1 or 2 equiv of t-BuLi afforded the mono- or dilithiated allylsilanes, which crystallize as a tetramer and a hexamer from pentane. The product selectivity in trapping reactions is influenced by the ability of both the solvent and the electrophile to coordinate the lithium center.Entities:
Year: 2006 PMID： 16787051 DOI： 10.1021/ja061286w
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419