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Literature DB >> 16779478

A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation.

So-Hye Cho¹, Baoqing Ma, SonBinh T Nguyen, Joseph T Hupp, Thomas E Albrecht-Schmitt.

Abstract

A new microporous metal-organic framework compound featuring chiral (salen)Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.

Entities: Chemical

Year: 2006 PMID： 16779478 DOI： 10.1039/b600408c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

24 in total

1. A series of isoreticular chiral metal-organic frameworks as a tunable platform for asymmetric catalysis.

Authors: Liqing Ma; Joseph M Falkowski; Carter Abney; Wenbin Lin
Journal: Nat Chem Date: 2010-07-25 Impact factor: 24.427

2. Surface modification and functionalization of nanoscale metal-organic frameworks for controlled release and luminescence sensing.

Authors: William J Rieter; Kathryn M L Taylor; Wenbin Lin
Journal: J Am Chem Soc Date: 2007-07-24 Impact factor: 15.419

3. One-dimensional imidazole aggregate in aluminium porous coordination polymers with high proton conductivity.

Authors: Sareeya Bureekaew; Satoshi Horike; Masakazu Higuchi; Motohiro Mizuno; Takashi Kawamura; Daisuke Tanaka; Nobuhiro Yanai; Susumu Kitagawa
Journal: Nat Mater Date: 2009-09-06 Impact factor: 43.841

4. Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene.

Authors: Sheng-Chang Xiang; Zhangjing Zhang; Cong-Gui Zhao; Kunlun Hong; Xuebo Zhao; De-Rong Ding; Ming-Hua Xie; Chuan-De Wu; Madhab C Das; Rachel Gill; K Mark Thomas; Banglin Chen
Journal: Nat Commun Date: 2011-02-22 Impact factor: 14.919

Review 10. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.

Authors: Timothy R Cook; Yao-Rong Zheng; Peter J Stang
Journal: Chem Rev Date: 2012-11-02 Impact factor: 60.622

A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation.

1. A series of isoreticular chiral metal-organic frameworks as a tunable platform for asymmetric catalysis.

2. Surface modification and functionalization of nanoscale metal-organic frameworks for controlled release and luminescence sensing.

3. One-dimensional imidazole aggregate in aluminium porous coordination polymers with high proton conductivity.

4. Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene.

5. Anhydrous proton conduction at 150 °C in a crystalline metal-organic framework.

6. Photoreactivity examined through incorporation in metal-organic frameworks.

7. Entrapment of metal clusters in metal-organic framework channels by extended hooks anchored at open metal sites.

8. catena-Poly[[tetra-μ(3)-isonicotinato-μ(3)-oxalato-μ(2)-oxalato-disamarium(III)disilver(I)] dihydrate].

9. HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin.

Review 10. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials.