| Literature DB >> 16774307 |
Abstract
A quantum-classical bracket is proposed and is shown to satisfy the Jacobi identity, in contrast to previous definitions that obey this property only up to higher order terms in the Planck constant variant Planck's over 2pi. The Jacobi identity is required of a true Lie bracket and ensures that the Lie bracket of constants of motion is also a constant of motion. An explicit calculation of the Jacobi identity highlights the difference between the proposed and traditional definitions. A further example illustrates that the proposed bracket generates a more consistent quantum-classical dynamics than the traditional bracket. The traditional quantum-classical dynamics in the Henon-Heiles system diverges due to higher order variant Planck's over 2pi terms. The divergence is eliminated with the proposed bracket.Year: 2006 PMID: 16774307 DOI: 10.1063/1.2200342
Source DB: PubMed Journal: J Chem Phys ISSN: 0021-9606 Impact factor: 3.488