Literature DB >> 16771483

Amineborane-based chemical hydrogen storage: enhanced ammonia borane dehydrogenation in ionic liquids.

Martin E Bluhm1, Mark G Bradley, Robert Butterick, Upal Kusari, Larry G Sneddon.   

Abstract

Ionic liquids are shown to provide advantageous media for amineborane-based chemical hydrogen storage systems. Both the extent and rate of hydrogen release from ammonia borane dehydrogenation are significantly increased at 85, 90, and 95 degrees C when the reactions are carried out in 1-butyl-3-methylimidazolium chloride compared to analogous solid-state reactions. NMR studies in conjunction with DFT/GIAO chemical shift calculations indicate that both polyaminoborane and the diammoniate of diborane, [(NH3)2BH2+]BH4-, are initial products in the reactions.

Entities:  

Year:  2006        PMID： 16771483     DOI： 10.1021/ja062085v

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  17 in total

1.  Dehydrogenation of ammonia borane through the third equivalent of hydrogen.

Authors:  Xingyue Zhang; Lisa Kam; Travis J Williams
Journal:  Dalton Trans       Date:  2016-05-04       Impact factor: 4.390

2.  A robust, air-stable, reusable ruthenium catalyst for dehydrogenation of ammonia borane.

Authors:  Brian L Conley; Denver Guess; Travis J Williams
Journal:  J Am Chem Soc       Date:  2011-08-18       Impact factor: 15.419

3.  Stability and molecular properties of the boron-nitrogen alternating analogs of azulene and naphthalene: a computational study.

Authors:  Anderson José Lopes Catão; Alejandro López-Castillo
Journal:  J Mol Model       Date:  2017-03-15       Impact factor: 1.810

4.  Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell.

Authors:  Shunichi Fukuzumi; Yusuke Yamada; Kenneth D Karlin
Journal:  Electrochim Acta       Date:  2012-11-01       Impact factor: 6.901

5.  A Three-Stage Mechanistic Model for Ammonia Borane Dehydrogenation by Shvo's Catalyst.

Authors:  Zhiyao Lu; Brian L Conley; Travis J Williams
Journal:  Organometallics       Date:  2012-08-30       Impact factor: 3.876

6.  High-pressure study of lithium amidoborane using Raman spectroscopy and insight into dihydrogen bonding absence.

Authors:  Shah Najiba; Jiuhua Chen
Journal:  Proc Natl Acad Sci U S A       Date:  2012-10-31       Impact factor: 11.205

7.  Storage of molecular hydrogen in an ammonia borane compound at high pressure.

Authors:  Yu Lin; Wendy L Mao; Ho-Kwang Mao
Journal:  Proc Natl Acad Sci U S A       Date:  2009-05-04       Impact factor: 11.205

8.  Metal-Free Addition/Head-to-Tail Polymerization of Transient Phosphinoboranes, RPH-BH2: A Route to Poly(alkylphosphinoboranes).

Authors:  Christian Marquardt; Titel Jurca; Karl-Christian Schwan; Andreas Stauber; Alexander V Virovets; George R Whittell; Ian Manners; Manfred Scheer
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-02       Impact factor: 15.336

Review 9.  Iron Catalyzed Dehydrocoupling of Amine- and Phosphine-Boranes.

Authors:  Nathan T Coles; Ruth L Webster
Journal:  Isr J Chem       Date:  2017-07-27       Impact factor: 3.333

10.  Molybdenum catalyzed ammonia borane dehydrogenation: oxidation state specific mechanisms.

Authors:  Joshua A Buss; Guy A Edouard; Christine Cheng; Jade Shi; Theodor Agapie
Journal:  J Am Chem Soc       Date:  2014-07-30       Impact factor: 15.419
View more

北京卡尤迪生物科技股份有限公司 © 2022-2023.