Literature DB >> 16771313

Acidoswitchable NLO-phores: benzimidazolo[2,3-b]oxazolidines.

Lionel Sanguinet1, Jean-Luc Pozzo, Maxime Guillaume, Benoît Champagne, Frédéric Castet, Laurent Ducasse, Etienne Maury, Jérémy Soulié, Fabien Mançois, Frédéric Adamietz, Vincent Rodriguez.   

Abstract

This paper presents a series of acidoswitchable NLO-phores combining the 9-methylbenzimidazolo[2,3-b]oxazolidine core with various pi systems such as phenylethenyl, phenylethynyl, and naphthylethenyl. All the prepared derivatives are shown to display acidochromic behavior at ambient temperature. The remarkable contrast in the NLO response along the reversible transformations observed in HRS experiments is rationalized by high level theoretical calculations.

Entities:  

Year:  2006        PMID: 16771313     DOI: 10.1021/jp060825g

Source DB:  PubMed          Journal:  J Phys Chem B        ISSN: 1520-5207            Impact factor:   2.991


  1 in total

1.  Imidazole as a parent π-conjugated backbone in charge-transfer chromophores.

Authors:  Jiří Kulhánek; Filip Bureš
Journal:  Beilstein J Org Chem       Date:  2012-01-05       Impact factor: 2.883

  1 in total

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