Literature DB >> 16767274

13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84 vs. Sc2C2@C82.

Yuko Iiduka1, Takatsugu Wakahara, Koji Nakajima, Takahiro Tsuchiya, Tsukasa Nakahodo, Yutaka Maeda, Takeshi Akasaka, Naomi Mizorogi, Shigeru Nagase.   

Abstract

Although Sc2C84 has been widely believed to have the form Sc2@C84, the present 13C NMR study reveals that it is a scandium carbide metallofullerene, Sc2C2@C82, which has a C82(C(3v)) cage.

Entities:  

Year:  2006        PMID: 16767274     DOI: 10.1039/b601738j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  6 in total

1.  "Dancing inside the ball": the structures and nonlinear optical properties of three Sc2S@C3v(8)-C82 isomers.

Authors:  Feng-Wei Gao; Ying Gao; Li-Jie Wang; Hong-Liang Xu; Shi-Ling Sun; Zhong-Min Su
Journal:  J Mol Model       Date:  2015-09-15       Impact factor: 1.810

2.  Selective arc-discharge synthesis of Dy2S-clusterfullerenes and their isomer-dependent single molecule magnetism.

Authors:  Chia-Hsiang Chen; Denis S Krylov; Stanislav M Avdoshenko; Fupin Liu; Lukas Spree; Ravi Yadav; Antonis Alvertis; Liviu Hozoi; Konstantin Nenkov; Aram Kostanyan; Thomas Greber; Anja U B Wolter; Alexey A Popov
Journal:  Chem Sci       Date:  2017-06-30       Impact factor: 9.825

3.  Confining the spin between two metal atoms within the carbon cage: redox-active metal-metal bonds in dimetallofullerenes and their stable cation radicals.

Authors:  Nataliya A Samoylova; Stanislav M Avdoshenko; Denis S Krylov; Hannah R Thompson; Amelia C Kirkhorn; Marco Rosenkranz; Sandra Schiemenz; Frank Ziegs; Anja U B Wolter; Shangfeng Yang; Steven Stevenson; Alexey A Popov
Journal:  Nanoscale       Date:  2017-06-14       Impact factor: 7.790

4.  Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy-Oxide Clusterfullerene Dy2O@C82.

Authors:  Wei Yang; Georgios Velkos; Fupin Liu; Svetlana M Sudarkova; Yaofeng Wang; Jiaxin Zhuang; Hanning Zhang; Xiang Li; Xingxing Zhang; Bernd Büchner; Stanislav M Avdoshenko; Alexey A Popov; Ning Chen
Journal:  Adv Sci (Weinh)       Date:  2019-08-15       Impact factor: 16.806

5.  High blocking temperatures for DyScS endohedral fullerene single-molecule magnets.

Authors:  Wenting Cai; Joshua D Bocarsly; Ashley Gomez; Rony J Letona Lee; Alejandro Metta-Magaña; Ram Seshadri; Luis Echegoyen
Journal:  Chem Sci       Date:  2020-11-02       Impact factor: 9.825

6.  Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc2 TiC@Ih -C80 , Sc2 TiC@D5h -C80 and Sc2 TiC2 @Ih -C80 : Metal Size Tuning of the Ti(IV) /Ti(III) Redox Potentials.

Authors:  Katrin Junghans; Kamran B Ghiassi; Nataliya A Samoylova; Qingming Deng; Marco Rosenkranz; Marilyn M Olmstead; Alan L Balch; Alexey A Popov
Journal:  Chemistry       Date:  2016-07-26       Impact factor: 5.236

  6 in total

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