Literature DB >> 16767270

Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes.

Pierre de Frémont1, Edwin D Stevens, Manuel R Fructos, M Mar Díaz-Requejo, Pedro J Pérez, Steven P Nolan.   

Abstract

A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.

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Year:  2006        PMID： 16767270     DOI： 10.1039/b601547f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Synergistic Peptide and Gold Catalysis: Enantioselective Addition of Branched Aldehydes to Allenamides.

Authors:  Leo D M Nicholls; Helma Wennemers
Journal:  Chemistry       Date:  2021-10-13       Impact factor: 5.020

2.  The role of silver additives in gold-mediated C-H functionalisation.

Authors:  Scott R Patrick; Ine I F Boogaerts; Sylvain Gaillard; Alexandra M Z Slawin; Steven P Nolan
Journal:  Beilstein J Org Chem       Date:  2011-07-01       Impact factor: 2.883

3.  Anatomy of gold catalysts: facts and myths.

Authors:  Beatrice Ranieri; Imma Escofet; Antonio M Echavarren
Journal:  Org Biomol Chem       Date:  2015-06-09       Impact factor: 3.876

4.  Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate.

Authors:  Manuel R Fructos; Juan Urbano; M Mar Díaz-Requejo; Pedro J Pérez
Journal:  Beilstein J Org Chem       Date:  2015-11-20       Impact factor: 2.883
  4 in total

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