Literature DB >> 16758032

A key step in the formation of acrylic acid from CO2 and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex.

Reinald Fischer1, Jens Langer, Astrid Malassa, Dirk Walther, Helmar Görls, Gavin Vaughan.   

Abstract

The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.

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Year:  2006        PMID： 16758032     DOI： 10.1039/b603540j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Bis[μ-1,2-bis-(diphenyl-phosphino)methane-κP:P']bis-[(η-ethene)nickel(0)] toluene disolvate.

Authors:  Jens Langer; Reinhald Fischer; Helmar Görls; Dirk Walther
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2008-01-25

2.  Crystal structure of bis-[1,3-bis-(di-phenyl-phosphan-yl)propane-κ(2) P,P']platinum(II) dichloride chloro-form penta-solvate.

Authors:  Bradley G Anderson; Sarah A Hoyte; John L Spencer
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2015-01-28

3.  A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO2/ethylene coupling.

Authors:  Ioana Knopf; Daniel Tofan; Dirk Beetstra; Abdulaziz Al-Nezari; Khalid Al-Bahily; Christopher C Cummins
Journal:  Chem Sci       Date:  2016-10-11       Impact factor: 9.825
  3 in total

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