| Literature DB >> 16758029 |
Guang Zhu1, Kevin E Janak, Gerard Parkin.
Abstract
Oxidative addition of H2 and D2 to the anthracene complex (eta6-AnH)Mo(PMe3)3 giving (eta4-AnH)Mo(PMe3)3X2 (X = H, D) is characterized by a normal equilibrium isotope effect (KH/KD > 1) at temperatures close to ambient; calculations on (eta4-AnH)Mo(PH3)3H2 indicate that this is a consequence of relatively low energy Mo-H vibrational modes.Entities:
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Year: 2006 PMID： 16758029 DOI： 10.1039/b604159k
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222