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Literature DB >> 16756275

Highly selective cobalt-catalyzed hydrovinylation of styrene.

Michiel M P Grutters¹, Christian Müller, Dieter Vogt.

Abstract

The hydrovinylation reaction is a codimerization of a 1,3-diene or vinyl arene and ethene with great potential for fine chemicals and pharmaceuticals. For the first time, enantioselective cobalt-catalyzed hydrovinylations of styrene were achieved with a cobalt-based system bearing a chiral bis(phosphine)amide ligand.

Entities: Chemical

Year: 2006 PMID： 16756275 DOI： 10.1021/ja058095y

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

14 in total

1. Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vi-nylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes.

Authors: Souvagya Biswas; Aibin Zhang; Balaram Raya; T V RajanBabu
Journal: Adv Synth Catal Date: 2014-07-01 Impact factor: 5.837

2. Asymmetric hydrovinylation of vinylindoles. A facile route to cyclopenta[g]indole natural products (+)-cis-trikentrin A and (+)-cis-trikentrin B.

Authors: Wang Liu; Hwan Jung Lim; T V RajanBabu
Journal: J Am Chem Soc Date: 2012-03-13 Impact factor: 15.419

3. Asymmetric hydrovinylation of 1-vinylcycloalkenes. Reagent control of regio- and stereoselectivity.

Authors: Jordan P Page; T V RajanBabu
Journal: J Am Chem Soc Date: 2012-03-30 Impact factor: 15.419

4. Asymmetric hydrovinylation of unactivated linear 1,3-dienes.

Authors: Rakesh K Sharma; T V RajanBabu
Journal: J Am Chem Soc Date: 2010-03-17 Impact factor: 15.419

5. A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins.

Authors: Souvagya Biswas; Mahesh M Parsutkar; Stanley M Jing; Vinayak V Pagar; James H Herbort; T V RajanBabu
Journal: Acc Chem Res Date: 2021-11-30 Impact factor: 22.384

Highly selective cobalt-catalyzed hydrovinylation of styrene.

1. Triarylphosphine Ligands with Hemilabile Alkoxy Groups. Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vi-nylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes.

2. Asymmetric hydrovinylation of vinylindoles. A facile route to cyclopenta[g]indole natural products (+)-cis-trikentrin A and (+)-cis-trikentrin B.

3. Asymmetric hydrovinylation of 1-vinylcycloalkenes. Reagent control of regio- and stereoselectivity.

4. Asymmetric hydrovinylation of unactivated linear 1,3-dienes.

5. A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins.

6. In Pursuit of an Ideal C-C Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins.

7. Efficient, selective, and green: catalyst tuning for highly enantioselective reactions of ethylene.

Review 8. Transition-metal-catalyzed laboratory-scale carbon-carbon bond-forming reactions of ethylene.

9. Asymmetric Catalysis with Ethylene. Synthesis of Functionalized Chiral Enolates.

10. Selective [1,4]-Hydrovinylation of 1,3-Dienes with Unactivated Olefins Enabled by Iron Diimine Catalysts.