Literature DB >> 16749816

Synthesis of Im3[Re3mu3-S)(mu-S3)Br9]Br (Im = 1-ethyl-3-methylimidazolium) by means of an ionic liquid.

Hideshi Sakamoto1, Yusuke Watanabe, Taro Saito.   

Abstract

Reaction of [Re3(mu3-S)(mu-S2)3Cl6]Cl with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and aluminum bromide (AlBr3) formed a new trinuclear rhenium sulfide cluster compound Im3[Re3(mu3-S)(mu-S)3Br9]Br with nine terminal bromo ligands.

Entities:  

Year:  2006        PMID: 16749816     DOI: 10.1021/ic060428k

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  Ionic liquid cations as methylation agent for extremely weak chalcogenido metalate nucleophiles.

Authors:  Bertram Peters; Silke Santner; Carsten Donsbach; Pascal Vöpel; Bernd Smarsly; Stefanie Dehnen
Journal:  Chem Sci       Date:  2019-04-22       Impact factor: 9.825

  1 in total

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