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Literature DB >> 16734455

Synthesis and structure of a stable pentavalent-uranyl coordination polymer.

Louise Natrajan¹, Fabien Burdet, Jacques Pécaut, Marinella Mazzanti.

Abstract

The polymeric complex {[UO2Py5][KI2Py2]}n was isolated by controlled oxidation of uranium tris-iodide in pyridine and structurally characterized using X-ray diffraction. The described synthetic method allows us to isolate a stable derivative of the elusive pentavalent UO2+ species providing a potential starting material for the development of anhydrous UO2+ coordination chemistry.

Entities: Chemical

Year: 2006 PMID： 16734455 DOI： 10.1021/ja0609809

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

8 in total

1. Structural/electronic properties and reaction energies of a series of mono- and bis-uranyl dihalides equatorially coordinated by N/O ligands.

Authors: Jun Yao; Yong-Ming Wang; Qing-Jiang Pan; Yuan-Ru Guo; Hong-Xing Zhang
Journal: J Mol Model Date: 2014-05-29 Impact factor: 1.810

2. Uranyl oxo activation and functionalization by metal cation coordination.

Authors: Polly L Arnold; Anne-Frédérique Pécharman; Emmalina Hollis; Ahmed Yahia; Laurent Maron; Simon Parsons; Jason B Love
Journal: Nat Chem Date: 2010-11-23 Impact factor: 24.427

3. Relativistic theoretical studies on hydrogen bonds and the electronic structure of aqueous solvated bis(uranyl) complex: an insight into explicit and/or implicit solvent effects.

Authors: Yuan-Ru Guo; Xin Zhou; Qing-Jiang Pan
Journal: J Mol Model Date: 2013-05-12 Impact factor: 1.810

4. Axially Symmetric U-O-Ln- and U-O-U-Containing Molecules from the Control of Uranyl Reduction with Simple f-Block Halides.

Authors: Polly L Arnold; Bradley E Cowie; Markéta Suvova; Markus Zegke; Nicola Magnani; Eric Colineau; Jean-Christophe Griveau; Roberto Caciuffo; Jason B Love
Journal: Angew Chem Int Ed Engl Date: 2017-08-07 Impact factor: 15.336

Synthesis and structure of a stable pentavalent-uranyl coordination polymer.

1. Structural/electronic properties and reaction energies of a series of mono- and bis-uranyl dihalides equatorially coordinated by N/O ligands.

2. Uranyl oxo activation and functionalization by metal cation coordination.

3. Relativistic theoretical studies on hydrogen bonds and the electronic structure of aqueous solvated bis(uranyl) complex: an insight into explicit and/or implicit solvent effects.

4. Axially Symmetric U-O-Ln- and U-O-U-Containing Molecules from the Control of Uranyl Reduction with Simple f-Block Halides.

5. Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin.

6. The effect of iron binding on uranyl(v) stability.

7. Photoluminescence of Pentavalent Uranyl Amide Complexes.

8. Double uranium oxo cations derived from uranyl by borane or silane reduction.