Adsorption of zinc on natural sediment of Tafna River (Algeria).

The environmental impact of metal additions to sediment depends on its sorption ability. The paper presents a study of zinc adsorption using the experiment data on natural sediment of Tafna River in northwest of Algeria. The effect of various operating variables, namely initial concentration, mass of sediment, and contact time, have been studied. The optimum contact time needed to reach equilibrium is of the order of 30 min and is independent of initial concentration and mass of zinc ions. The extent of adsorption increases with increase of concentration, and with decrease of adsorbent mass. The content of carbonate in sediment increases the adsorption indicating the active support material towards zinc ions. A batch sorption model, which assumes the pseudo-second-order mechanism, is developed to predict the rate constant of the sorption, the equilibrium sorption capacity and the initial sorption rate with the effect of initial zinc ion concentration and sediment dose. Various thermodynamic parameters, such as DeltaG degrees , DeltaH degrees and DeltaS degrees , have been calculated. The thermodynamics of zinc ion/sediment system indicates spontaneous, endothermic and randomness nature of the process.