Literature DB >> 16719455

all-anti-octasilane: conformation control of silicon chains using the bicyclic trisilane as a building block.

Aiko Fukazawa1, Hayato Tsuji, Kohei Tamao.   

Abstract

The perfect all-anti-octasilane composed of two bicyclic trisilane units with trimethylsilyl groups at the termini has been synthesized. Its X-ray crystal structure and spectroscopic data demonstrate the effective sigma-delocalization over the silicon framework, which is a definitive difference from the unconstrained n-Si8Me18.

Entities:  

Year:  2006        PMID： 16719455     DOI： 10.1021/ja0616231

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Self-assembled monolayers of oligosilane on the silicon (001) surface: molecular dynamics simulations.

Authors:  Li Zhao; Xue-Mei Duan; Xiang-Gui Xue; Ming-Hui Li; Ze-Sheng Li
Journal:  J Mol Model       Date:  2010-06-10       Impact factor: 1.810

2.  Conformational Control of Polysilanes: Use of CH(2) Spacers in the Silicon Backbone.

Authors:  Andreas Wallner; Johann Hlina; Harald Wagner; Judith Baumgartner; Christoph Marschner
Journal:  Organometallics       Date:  2011-07-11       Impact factor: 3.876

3.  Rearrangement/Fragmentation Reactions of Oligosilanes with Aluminum Chloride.

Authors:  Harald Wagner; Judith Baumgartner; Christoph Marschner; Peter Poelt
Journal:  Organometallics       Date:  2011-07-11       Impact factor: 3.876

4.  1,1,4,4-Tetra-tert-butyl-1,4-dichloro-2,2,3,3-tetra-phenyl-tetra-silane.

Authors:  Kyohei Otsuka; Shintaro Ishida; Soichiro Kyushin
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-01-18

5.  σ-Bond electron delocalization of branched oligogermanes and germanium containing oligosilanes.

Authors:  Johann Hlina; Rainer Zitz; Harald Wagner; Filippo Stella; Judith Baumgartner; Christoph Marschner
Journal:  Inorganica Chim Acta       Date:  2014-10-01       Impact factor: 2.545

6.  Incorporating Methyl and Phenyl Substituted Stannylene Units into Oligosilanes. The Influence on Optical Absorption Properties.

Authors:  Filippo Stella; Christoph Marschner; Judith Baumgartner
Journal:  Molecules       Date:  2017-12-12       Impact factor: 4.411
  6 in total

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