Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Evidence of hollow golden cages.

Literature DB >> 16714382

Evidence of hollow golden cages.

Satya Bulusu¹, Xi Li, Lai-Sheng Wang, Xiao Cheng Zeng.

Abstract

The fullerenes are the first "free-standing" elemental hollow cages identified by spectroscopy experiments and synthesized in the bulk. Here, we report experimental and theoretical evidence of hollow cages consisting of pure metal atoms, Au(n)(-) (n = 16-18); to our knowledge, free-standing metal hollow cages have not been previously detected in the laboratory. These hollow golden cages ("bucky gold") have an average diameter >5.5 A, which can easily accommodate one guest atom inside.

Entities: Chemical

Year: 2006 PMID： 16714382 PMCID： PMC1482493 DOI： 10.1073/pnas.0600637103

Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN： 0027-8424 Impact factor: 11.205

17 in total

1. Generalized Gradient Approximation Made Simple.

Authors:
Journal: Phys Rev Lett Date: 1996-10-28 Impact factor: 9.161

2. Experimental observation and confirmation of icosahedral W@Au12 and Mo@Au12 molecules.

Authors: Xi Li; Boggavarapu Kiran; Jun Li; Hua-Jin Zhai; Lai-Sheng Wang
Journal: Angew Chem Int Ed Engl Date: 2002-12-16 Impact factor: 15.336

3. Au20: a tetrahedral cluster.

Authors: Jun Li; Xi Li; Hua-Jin Zhai; Lai-Sheng Wang
Journal: Science Date: 2003-02-07 Impact factor: 47.728

4. Theoretical chemistry of gold.

Authors: Pekka Pyykkö
Journal: Angew Chem Int Ed Engl Date: 2004-08-27 Impact factor: 15.336

5. Experimental and theoretical investigation of the electronic and geometrical structures of the Au32 cluster.

Authors: Min Ji; Xiao Gu; Xi Li; Xingao Gong; Jun Li; Lai-Sheng Wang
Journal: Angew Chem Int Ed Engl Date: 2005-11-04 Impact factor: 15.336

6. Structure and shape variations in intermediate-size copper clusters.

Authors: Mingli Yang; Koblar A Jackson; Christof Koehler; Thomas Frauenheim; Julius Jellinek
Journal: J Chem Phys Date: 2006-01-14 Impact factor: 3.488

7. Structure of Au8: planar or nonplanar?

Authors: Young-Kyu Han
Journal: J Chem Phys Date: 2006-01-14 Impact factor: 3.488

8. Au32: a 24-carat golden fullerene.

Authors: Mikael P Johansson; Dage Sundholm; Juha Vaara
Journal: Angew Chem Int Ed Engl Date: 2004-05-10 Impact factor: 15.336

9. Icosahedral WAu12: a predicted closed-shell species, stabilized by aurophilic attraction and relativity and in accord with the 18-electron rule.

Authors: Pekka Pyykkö; Nino Runeberg
Journal: Angew Chem Int Ed Engl Date: 2002-06-17 Impact factor: 15.336

10. Au42: an alternative icosahedral golden fullerene cage.

Authors: Yi Gao; Xiao Cheng Zeng
Journal: J Am Chem Soc Date: 2005-03-23 Impact factor: 15.419

14 in total

1. Observation of an all-boron fullerene.

Authors: Hua-Jin Zhai; Ya-Fan Zhao; Wei-Li Li; Qiang Chen; Hui Bai; Han-Shi Hu; Zachary A Piazza; Wen-Juan Tian; Hai-Gang Lu; Yan-Bo Wu; Yue-Wen Mu; Guang-Feng Wei; Zhi-Pan Liu; Jun Li; Si-Dian Li; Lai-Sheng Wang
Journal: Nat Chem Date: 2014-07-13 Impact factor: 24.427

2. The topology of fullerenes.

Authors: Peter Schwerdtfeger; Lukas N Wirz; James Avery
Journal: Wiley Interdiscip Rev Comput Mol Sci Date: 2015-01

3. Structural characteristics and chemical reactivity of gold-based clusters Au_n (n = 16, 17) toward lone pairs.

Authors: Nguyen Huu Tho; Thanh Q Bui; Nguyen Thanh Si; Pham Vu Nhat; Nguyen Thi Ai Nhung
Journal: J Mol Model Date: 2022-02-07 Impact factor: 1.810

4. Mesomorphic lamella rolling of au in vacuum.

Authors: Chang-Ning Huang; Shuei-Yuan Chen; Pouyan Shen
Journal: Nanoscale Res Lett Date: 2009-07-18 Impact factor: 4.703

5. Water-Driven Assembly of Laser Ablation-Induced Au Condensates as Mesomorphic Nano- and Micro-Tubes.

Authors: Chang-Ning Huang; Shuei-Yuan Chen; Yuyuan Zheng; Pouyan Shen
Journal: Nanoscale Res Lett Date: 2009-06-06 Impact factor: 4.703

6. Nonlocal effects on the structural transition of gold clusters from planar to three-dimensional geometries.

Authors: Ping Wu; Qingxiu Liu; Gang Chen
Journal: RSC Adv Date: 2019-07-05 Impact factor: 3.361

7. Formation and Stability of Low-Dimensional Structures for Group VIIIB and IB Transition Metals: The Role of sd⁴ Hybridization.

Authors: Jianhui Yang; Qiuju Zhang; Liang Chen; Gang Wang; Xiaolong Chen
Journal: Adv Sci (Weinh) Date: 2016-01-21 Impact factor: 16.806