Literature DB >> 16711606

Acyl migration during debenzylation of 1,3-di-O-benzyl-2-O-acylglycerols.

Lijian Yue1, Chenggang Zhang, Guolin Zhang.   

Abstract

In investigating the preparation of 2-acylglycerol by debenzylation of 1,3-di-O-benzyl-2-O-acylglycerol, twelve 1,3-di-O-benzyl-2-O-acylglycerols were synthesized. 2-O-Acyl moieties with one or more protons at the carbon atom adjacent to carbonyl group were found to migrate from C-2 to C-1 of the glycerol moiety during hydrogenation under Pd/C at room temperature.

Entities:  

Mesh:

Substances:

Year:  2006        PMID: 16711606     DOI: 10.1007/s11745-006-5101-y

Source DB:  PubMed          Journal:  Lipids        ISSN: 0024-4201            Impact factor:   1.880


  2 in total

1.  ON THE SITE OF ESTERIFICATION OF AMINO ACIDS TO SOLUBLE RNA.

Authors:  R WOLFENDEN; D H RAMMLER; F LIPMANN
Journal:  Biochemistry       Date:  1964-03       Impact factor: 3.162

2.  Acyl migration in 1,2-dipalmitoyl-sn-glycerol.

Authors:  D R Kodali; A Tercyak; D A Fahey; D M Small
Journal:  Chem Phys Lipids       Date:  1990-02       Impact factor: 3.329

  2 in total
  1 in total

1.  Triphenylphosphine reduction of saturated endoperoxides.

Authors:  Ihsan Erden; Christian Gärtner; M Saeed Azimi
Journal:  Org Lett       Date:  2009-09-03       Impact factor: 6.005

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.