Literature DB >> 16706502

Unusual ambiphilic carbenoid equivalent in amide cyclopropanation.

Kuo-Wei Lin1, Shiuan Yan, I-Lin Hsieh, Tu-Hsin Yan.   

Abstract

[reaction: see text] The titanium-methylene complexes derived from the TiCl(4)-Mg-CH(2)Cl(2) system serve as a novel class of ambiphilic carbenoid equivalents, which not only efficiently effect cyclopropanations of a variety amides but also exhibit high chemoselectivity.

Entities:  

Year:  2006        PMID: 16706502     DOI: 10.1021/ol060438p

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Cyclopropane-Fused N-Heterocycles via Aza-Heck-Triggered C(sp3)-H Functionalization Cascades.

Authors:  Changcheng Jing; Benjamin T Jones; Ross J Adams; John F Bower
Journal:  J Am Chem Soc       Date:  2022-09-09       Impact factor: 16.383

  1 in total

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