Literature DB >> 16704871

A simple, convenient and chemoselective formylation of sterols by Vilsmeier reagent.

Vandana Srivastava1, Arvind Singh Negi, J K Kumar, M M Gupta.   

Abstract

Vilsmeier reagent (DMF-POCl(3)) was used as an efficient formylating agent. Several sterols having sec-hydroxyl group at 3/17-position have been modified into respective formate esters. The method is simple, mild, chemoselective and provides sec-alcoholic protection in good yields.

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Year:  2006        PMID: 16704871     DOI: 10.1016/j.steroids.2006.03.005

Source DB:  PubMed          Journal:  Steroids        ISSN: 0039-128X            Impact factor:   2.668


  1 in total

1.  One-Flask Synthesis of Pyrazolo[3,4-d]pyrimidines from 5-Aminopyrazoles and Mechanistic Study.

Authors:  Wan-Ping Yen; Shuo-En Tsai; Naoto Uramaru; Hiroyuki Takayama; Fung Fuh Wong
Journal:  Molecules       Date:  2017-05-16       Impact factor: 4.411

  1 in total

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