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Literature DB >> 16704256

A tetracoordinated rhodium aminyl radical complex.

Pascal Maire¹, Martin Königsmann, Anandaram Sreekanth, Jeffrey Harmer, Arthur Schweiger, Hansjörg Grützmacher.

Abstract

A [16 + 1] valence electron configured rhodium aminyl radical complex could be synthesized and characterized in detail by pulse EPR spectroscopy and DFT calculations. The unpaired electron is delocalized over the metal center and two adjacent nitrogens. H-abstraction reactions from thiols and triethylsilane show that the spin density is predominantly localized on both nitrogens.

Entities: Chemical Gene

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Year: 2006 PMID： 16704256 DOI： 10.1021/ja0612798

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

6 in total

1. Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.

Authors: Yuichi Shimazaki; T Daniel P Stack; Tim Storr
Journal: Inorg Chem Date: 2009-09-07 Impact factor: 5.165

2. Synthesis and characterization of a series of structurally and electronically diverse Fe(II) complexes featuring a family of triphenylamido-amine ligands.

Authors: Patrina Paraskevopoulou; Lin Ai; Qiuwen Wang; Devender Pinnapareddy; Rama Acharyya; Rupam Dinda; Purak Das; Remle Celenligil-Cetin; Georgios Floros; Yiannis Sanakis; Amitava Choudhury; Nigam P Rath; Pericles Stavropoulos
Journal: Inorg Chem Date: 2010-01-04 Impact factor: 5.165

A tetracoordinated rhodium aminyl radical complex.

1. Detailed evaluation of the geometric and electronic structures of one-electron oxidized group 10 (Ni, Pd, and Pt) metal(II)-(disalicylidene)diamine complexes.

2. Synthesis and characterization of a series of structurally and electronically diverse Fe(II) complexes featuring a family of triphenylamido-amine ligands.

3. Defining the electronic and geometric structure of one-electron oxidized copper-bis-phenoxide complexes.

4. Metal-Diazo Radicals of α-Carbonyl Diazomethanes.

5. Scrutinizing metal-ligand covalency and redox non-innocence via nitrogen K-edge X-ray absorption spectroscopy.

6. Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands.