Literature DB >> 16683813

Unexpected chemical and electrochemical properties of M3N@C80 (M = Sc, Y, Er).

Claudia M Cardona1, Bevan Elliott, Luis Echegoyen.   

Abstract

The unexpected isomerization of N-ethyl [6,6]-pyrrolidino-Y3N@C80 to the [5,6] regioisomer is reported, as well as the synthesis, characterization, and electrochemical analysis of Er3N@C80 derivatives. A complete electrochemical study of the M3N@C80 species (M = Sc, Y, Er) and their derivatives is presented. We introduce electrochemistry as a new tool in the characterization of the [5,6] and [6,6] regioisomers of trimetallic nitride endohedral metallofullerenes.

Entities:  

Year:  2006        PMID: 16683813     DOI: 10.1021/ja061035n

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  8 in total

1.  Photoinduced charge transfer and electrochemical properties of triphenylamine I(h)-Sc3N@C80 donor-acceptor conjugates.

Authors:  Julio R Pinzón; Diana C Gasca; Shankara G Sankaranarayanan; Giovanni Bottari; Tomás Torres; Dirk M Guldi; Luis Echegoyen
Journal:  J Am Chem Soc       Date:  2009-06-10       Impact factor: 15.419

2.  "Dancing inside the ball": the structures and nonlinear optical properties of three Sc2S@C3v(8)-C82 isomers.

Authors:  Feng-Wei Gao; Ying Gao; Li-Jie Wang; Hong-Liang Xu; Shi-Ling Sun; Zhong-Min Su
Journal:  J Mol Model       Date:  2015-09-15       Impact factor: 1.810

3.  Electronic properties and 13C NMR structural study of Y3N@C88.

Authors:  Wujun Fu; Jianyuan Zhang; Hunter Champion; Tim Fuhrer; Hugo Azuremendi; Tianming Zuo; Jianfei Zhang; Kim Harich; Harry C Dorn
Journal:  Inorg Chem       Date:  2011-04-20       Impact factor: 5.165

4.  Endohedral fullerenes for organic photovoltaic devices.

Authors:  Russel B Ross; Claudia M Cardona; Dirk M Guldi; Shankara Gayathri Sankaranarayanan; Matthew O Reese; Nikos Kopidakis; Jeff Peet; Bright Walker; Guillermo C Bazan; Edward Van Keuren; Brian C Holloway; Martin Drees
Journal:  Nat Mater       Date:  2009-02-08       Impact factor: 43.841

5.  Selective complexation and reactivity of metallic nitride and oxometallic fullerenes with Lewis acids and use as an effective purification method.

Authors:  Steven Stevenson; Mary A Mackey; Jane E Pickens; Melissa A Stuart; Bridget S Confait; J Paige Phillips
Journal:  Inorg Chem       Date:  2009-12-21       Impact factor: 5.165

6.  A crystalline anionic complex of scandium nitride endometallofullerene: experimental observation of single-bonded (Sc3N@Ih-C80(-))2 dimers.

Authors:  Dmitri V Konarev; Leokadiya V Zorina; Salavat S Khasanov; Alexey A Popov; Akihiro Otsuka; Hideki Yamochi; Gunzi Saito; Rimma N Lyubovskaya
Journal:  Chem Commun (Camb)       Date:  2016-08-11       Impact factor: 6.222

7.  Reliable charge assessment on encapsulated fragment for endohedral systems.

Authors:  A J Stasyuk; M Solà; A A Voityuk
Journal:  Sci Rep       Date:  2018-02-13       Impact factor: 4.379

8.  Highly regioselective complexation of tungsten with Eu@C82/Eu@C84: interplay between endohedral and exohedral metallic units induced by electron transfer.

Authors:  Lipiao Bao; Pengyuan Yu; Ying Li; Changwang Pan; Wangqiang Shen; Peng Jin; Shuquan Liang; Xing Lu
Journal:  Chem Sci       Date:  2019-04-26       Impact factor: 9.825

  8 in total

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