| Literature DB >> 1667857 |
C Jones1, F Currie, M J Forster.
Abstract
The 1H- and 13C-n.m.r. data on the capsular polysaccharide (1) produced by Streptococcus pneumoniae type 4, the depyruvated polysaccharide (2), and a tetrasaccharide (3a) derived by Smith degradation of 2 were used as constraints on a computer-generated model of the conformation of 1 and to assess the effects of the pyruvic acetal substituent on the conformation. The dynamics of the polysaccharide systems and the influence of the pyruvic acetal were investigated using 13C-n.m.r. relaxation measurements.Entities:
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Year: 1991 PMID: 1667857 DOI: 10.1016/0008-6215(91)80051-n
Source DB: PubMed Journal: Carbohydr Res ISSN: 0008-6215 Impact factor: 2.104