| Literature DB >> 16678476 |
Mahmudur Rahman1, H James Harmon.
Abstract
Meso-tetra(4-sulfonatophenyl)porphyrin (TPPS) interacts with trinitrotoluene (TNT) and forms a 1:1 complex with a new absorbance peak at 422 nm. TNT quenches TPPS emission intensity at 645 and 702 nm when excited at 413 nm. The TPPS-TNT complex is formed in the ground state on the basis of a linear Stern-Volmer plot indicative of static quenching. The association constants determined from absorbance and fluorescence studies are in excellent agreement.Entities:
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Year: 2006 PMID: 16678476 DOI: 10.1016/j.saa.2006.01.029
Source DB: PubMed Journal: Spectrochim Acta A Mol Biomol Spectrosc ISSN: 1386-1425 Impact factor: 4.098