Literature DB >> 16671789

Rearrangement of homoallylic alcohols induced by DAST.

Sophie Canova1, Véronique Bellosta, Serge Mignani, Antony Bigot, Janine Cossy.   

Abstract

[reaction: see text] Treatment of beta,gamma-unsaturated monoprotected 1,2-diols with diethylaminosulfur trifluoride (DAST) allows the stereoselective formation of beta,gamma-unsaturated aldehydes in good yields and with a good transfer of chirality.

Entities:  

Year:  2006        PMID: 16671789     DOI: 10.1021/ol060529m

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  1 in total

1.  Triphosgene-amine base promoted chlorination of unactivated aliphatic alcohols.

Authors:  Andrés Villalpando; Caitlan E Ayala; Christopher B Watson; Rendy Kartika
Journal:  J Org Chem       Date:  2013-03-29       Impact factor: 4.354

  1 in total

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