| Literature DB >> 16650394 |
Sheng-Jie Hsu1, Hui-Chang Lin, Chun-Hung Lin.
Abstract
exo-Glycosyl carbonates were employed for inter- and intramolecular glycosylation reactions. A number of metallic Lewis Acids and solvents were examined to enhance the reactivity. The optimum conditions were found to be the use of AlCl3 in 1-nitropropane. The method was demonstrated to be useful for the intermolecular glycosyl transfer of several nucleophiles, including simple alcohols, sugars, and amino acid derivatives; however, intramolecular glycosylations were not successful.Entities:
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Year: 2006 PMID： 16650394 DOI： 10.1016/j.carres.2006.04.003
Source DB: PubMed Journal: Carbohydr Res ISSN： 0008-6215 Impact factor: 2.104