| Literature DB >> 16649752 |
Limei Qiu1, Fen Liu, Liangzhong Zhao, Wensheng Yang, Jiannian Yao.
Abstract
In the interaction of PVP with Pt nanoparticles <7 nm in size, charge transfer is from carbonyl groups in PVP to Pt nanoparticles, whereas in the interaction of PVP with bulk Pt or Pt nanoparticles >25 nm in size, charge transfer is from Pt metal to the polymer side chain of PVP. There exists a critical nanoparticle size between 7 and 25 nm that would lead to a switch in the electron donor-acceptor property.Entities:
Year: 2006 PMID: 16649752 DOI: 10.1021/la053071q
Source DB: PubMed Journal: Langmuir ISSN: 0743-7463 Impact factor: 3.882