Literature DB >> 16637608

Li+-catalyzed radical polymerization of simple terminal alkenes.

Kamesh Vyakaranam1, Josiah B Barbour, Josef Michl.   

Abstract

Solutions of Li+ salts of highly alkylated derivatives of the monocarbadodecaborate anion in 1,2-dichloroethane catalyze the radical polymerization of simple terminal alkenes, dienes, and alkynes under ambient conditions, initiated by azoisobutyronitrile, di-tert-butyl peroxide, or atmospheric air.

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Year:  2006        PMID： 16637608     DOI： 10.1021/ja060087+

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  3 in total

1.  H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.

Authors:  Christopher A Reed
Journal:  Acc Chem Res       Date:  2010-01-19       Impact factor: 22.384

2.  Gas-phase lithium cation basicity: revisiting the high basicity range by experiment and theory.

Authors:  Charly Mayeux; Peeter Burk; Jean-Francois Gal; Ivari Kaljurand; Ilmar Koppel; Ivo Leito; Lauri Sikk
Journal:  J Am Soc Mass Spectrom       Date:  2014-09-05       Impact factor: 3.109

3.  Vinyl Carbocations Generated under Basic Conditions and Their Intramolecular C-H Insertion Reactions.

Authors:  Benjamin Wigman; Stasik Popov; Alex L Bagdasarian; Brian Shao; Tyler R Benton; Chloé G Williams; Steven P Fisher; Vincent Lavallo; K N Houk; Hosea M Nelson
Journal:  J Am Chem Soc       Date:  2019-05-29       Impact factor: 15.419
  3 in total

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