Literature DB >> 16635584

Determination of structural modification in acid activated montmorillonite clay by FT-IR spectroscopy.

Beena Tyagi1, Chintan D Chudasama, Raksh V Jasra.   

Abstract

The structural modifications and the Bronsted acid sites generated during the acid treatment of montmorillonite clay with varied concentration of sulphuric acid was determined using FT-IR spectroscopy. Octahedral sheet is affected at low acid concentration resulting into the dissolution of cations; among them Mg2+ cations are prone to dissolve than Fe2+/3+ and Al3+. Tetrahedral sheet is affected at higher acid concentration. The partial substitution of octahedral Al3+ by Mg2+ or Fe2+/3+ cations and the presence of other non-smectite minerals such as kaolinites was also been clearly identified, thus making FT-IR spectroscopy as a rapid technique for monitoring the structural features of montmorillonite clay.

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Year:  2006        PMID: 16635584     DOI: 10.1016/j.saa.2005.07.018

Source DB:  PubMed          Journal:  Spectrochim Acta A Mol Biomol Spectrosc        ISSN: 1386-1425            Impact factor:   4.098


  12 in total

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