Literature DB >> 16633555

A facile and chemoselective conjugate reduction using polymethylhydrosiloxane (PMHS) and catalytic B(C6F5)3.

Srivari Chandrasekhar1, Gudise Chandrashekar, Marepally Srinivasa Reddy, Pabbaraja Srihari.   

Abstract

A highly chemoselective conjugate reduction of electron-deficient Michael acceptors, including alpha,beta-unsaturated ketones, carboxylic esters, nitriles and nitro compounds with PMHS in the presence of catalytic B(C6F5)3 is described.

Entities:  

Year:  2006        PMID： 16633555     DOI： 10.1039/b603610b

Source DB:  PubMed          Journal:  Org Biomol Chem        ISSN： 1477-0520            Impact factor:   3.876


  3 in total

1.  Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions.

Authors:  Trandon A Bender; Philippa R Payne; Michel R Gagné
Journal:  Nat Chem       Date:  2017-09-18       Impact factor: 24.427

2.  Silicon Industry Waste Polymethylhydrosiloxane-Mediated Benzotriazole Ring Cleavage: A Practical and Green Synthesis of Diverse Benzothiazoles.

Authors:  Mangal S Yadav; Anoop S Singh; Anand K Agrahari; Nidhi Mishra; Vinod K Tiwari
Journal:  ACS Omega       Date:  2019-04-11

3.  Defluorodearomatization: A Photocatalytic Birch-Like Reduction That Enables C-C Bond Formation and Provides Access to Unnatural Cannabinoids.

Authors:  Jon I Day; Sascha Grotjahn; Sameera Senaweera; Burkhard Koenig; Jimmie D Weaver Iii
Journal:  J Org Chem       Date:  2021-06-02       Impact factor: 4.354
  3 in total

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